IC7 samples in IC spaces (Fig. 2d; Supplementary Fig. S4b). Thus, IC7 corresponds to the hydrothermal component that directly precipitates from a hydrothermal plume and results in significant Fe- and Mn-enrichment in the sediment19. IC7 is comparable to the Fe-rich trend associated with the enrichment of REY in the Fe2O3 EY diagram2. A probable origin of the Fe-, Mn-, P- and REY-enriched sediments showing high IC7 scores was suggested to be a scavenging mechanism by Fe-oxyhydroxides in hydrothermal plumes which takes up various elements, including P and REY, from ambient seawater during advection through the water column and after settling on the seafloor19,20. Both IC1 and IC4 had generally loading patterns similar to highly positive P2O5 and REY, although only IC1 showed prominently positive Ce loading together with positive Mn loading (Supplementary Fig. S6). In the two-dimensional IC space spanned by IC1 and IC4 (Fig. 2e), the samples showing very high REY concentrations (REY + Ce > 1,000 ppm), generally zeolitic clay or pelagic red clay in lithology2?, were distributed in the positive domains of each IC. For IC1, the reference data of both biogenic calcium phosphate (Ca-phosphate) and Fe n oxides such as ferromanganese crusts and nodules were projected in the same domain as the high-IC1 REY-rich mud samples (Fig. 2e). A number of previous studies have demonstrated that biogenic XAV-939 site TAPI-2MedChemExpress TAPI-2 Ca-phosphate constituting the bones and teeth of marine vertebrates shows very high concentrations of REY and regulates the bulk REY abundance in pelagic sediments21?6. Moreover, hydrogenetically precipitated Mn oxides ( nO2) uptake Ce in seawater preferentially via oxidation of Ce (III) to Ce (IV)27?9, which can explain the very high loading of Ce exhibited by IC1. Hence, IC1 represents REY-rich mud concentrating both REY-enriched biogenic Ca-phosphate and Ce-enriched Fe n oxides. For IC4, however, the biogenic Ca-phosphate was projected in the positive domain of IC4, although the Fe n oxides were on the opposite side (IC4 < 0) in the IC space (Fig. 2e). Therefore, IC4 represents REY-rich mud with an abundance of biogenic Ca-phosphate but with a deficiency of hydrogenous Fe n oxides. In addition to the analytical error, several factors that potentially affect the ICA results were further checked individually, such as outliers in the dataset, the variability of the sample subsets between the Pacific and Indian oceans, and the recalculation of raw data to sum to 100 . The results of the sensitivity tests for such factors indicated that the geochemical ICs described above were statistically robust and valid (Supplementary Figs S8 16). To examine the manner in which the REY-enrichment ICs can be affected by dilution effects and by the element menu analysed, we performed additional ICA on samples without significant dilutions from biogenic carbonate and silica by using the selective variables of Fe2O3, MnO, CaO, P2O5, and all of the separated REY elements. This additional ICA (n = 1,575) resulted in extraction of essentially the same ICs as the original REY-enrichment ICs, i.e. IC1, IC4, and IC7 (Supplementary Fig. S17). The results of these robustness checks show that the original ICA result sufficiently extracted the essential geochemical features of both the REY-enrichment ICs and others from the comprehensive dataset.Checking the statistical robustness of independent components.Spatiotemporal distributions of independent components. By using the sedimentary.IC7 samples in IC spaces (Fig. 2d; Supplementary Fig. S4b). Thus, IC7 corresponds to the hydrothermal component that directly precipitates from a hydrothermal plume and results in significant Fe- and Mn-enrichment in the sediment19. IC7 is comparable to the Fe-rich trend associated with the enrichment of REY in the Fe2O3 EY diagram2. A probable origin of the Fe-, Mn-, P- and REY-enriched sediments showing high IC7 scores was suggested to be a scavenging mechanism by Fe-oxyhydroxides in hydrothermal plumes which takes up various elements, including P and REY, from ambient seawater during advection through the water column and after settling on the seafloor19,20. Both IC1 and IC4 had generally loading patterns similar to highly positive P2O5 and REY, although only IC1 showed prominently positive Ce loading together with positive Mn loading (Supplementary Fig. S6). In the two-dimensional IC space spanned by IC1 and IC4 (Fig. 2e), the samples showing very high REY concentrations (REY + Ce > 1,000 ppm), generally zeolitic clay or pelagic red clay in lithology2?, were distributed in the positive domains of each IC. For IC1, the reference data of both biogenic calcium phosphate (Ca-phosphate) and Fe n oxides such as ferromanganese crusts and nodules were projected in the same domain as the high-IC1 REY-rich mud samples (Fig. 2e). A number of previous studies have demonstrated that biogenic Ca-phosphate constituting the bones and teeth of marine vertebrates shows very high concentrations of REY and regulates the bulk REY abundance in pelagic sediments21?6. Moreover, hydrogenetically precipitated Mn oxides ( nO2) uptake Ce in seawater preferentially via oxidation of Ce (III) to Ce (IV)27?9, which can explain the very high loading of Ce exhibited by IC1. Hence, IC1 represents REY-rich mud concentrating both REY-enriched biogenic Ca-phosphate and Ce-enriched Fe n oxides. For IC4, however, the biogenic Ca-phosphate was projected in the positive domain of IC4, although the Fe n oxides were on the opposite side (IC4 < 0) in the IC space (Fig. 2e). Therefore, IC4 represents REY-rich mud with an abundance of biogenic Ca-phosphate but with a deficiency of hydrogenous Fe n oxides. In addition to the analytical error, several factors that potentially affect the ICA results were further checked individually, such as outliers in the dataset, the variability of the sample subsets between the Pacific and Indian oceans, and the recalculation of raw data to sum to 100 . The results of the sensitivity tests for such factors indicated that the geochemical ICs described above were statistically robust and valid (Supplementary Figs S8 16). To examine the manner in which the REY-enrichment ICs can be affected by dilution effects and by the element menu analysed, we performed additional ICA on samples without significant dilutions from biogenic carbonate and silica by using the selective variables of Fe2O3, MnO, CaO, P2O5, and all of the separated REY elements. This additional ICA (n = 1,575) resulted in extraction of essentially the same ICs as the original REY-enrichment ICs, i.e. IC1, IC4, and IC7 (Supplementary Fig. S17). The results of these robustness checks show that the original ICA result sufficiently extracted the essential geochemical features of both the REY-enrichment ICs and others from the comprehensive dataset.Checking the statistical robustness of independent components.Spatiotemporal distributions of independent components. By using the sedimentary.
